Anmol Chemicals is the pioneer manufacturers of Methyl salicylate, Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Methyl salicylate made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Methyl salicylate is in these pages.
The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Methyl Salicylate SDS GHS, MSDS Sheet

Arabic مصنعي ساليسيلات الميثيل
Dutch Methyl salicylaat fabrikanten
German Methyl Salicylate Hersteller
Italian Produttori di salicilato di metile
Spanish Fabricantes de salicilato de metilo
French Fabricants de Salicylate de méthyle
Portuguese Fabricantes de salicilato de metila

Methyl Salicylate SDS GHS, MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: 2-Hydroxybenzoic acid Methyl ester, Methyl 2-hydroxybenzoate, Oil of wintergreen, Methoxybenzoic Acid.
CAS No.: 119-36-8
EINECS EC Number: 204-317-7
Molecular Weight: 152.15
Chemical Formula: 2-(HO)C6H4CO2CH3
Recommended usage: Industrial Manufacturing.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labeling according Regulation (EC) No 1272/2008


GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H319: Causes serious eye irritation.

Precautionary statements:P337+P313P
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22, R36
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Methyl Salicylate
CAS No.: 119-36-8
EINECS EC Number: 204-317-7
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Combustible at high temperature. Vapors can travel to a source of ignition and flash back.
Auto-Ignition Temperature: 454C.
Flash Points: 96C Closed Cup.
Flammable Limits: Not available.
Products of Combustion: Fumes, Carbon dioxide & Carbon Monoxide.
Fire: Methyl Salicylate is flammable on heating.
Explosion: Expslosive on heating.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit carbon monoxide. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Do not use combustible materials such as sawdust. Provide ventilation.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Methyl Salicylate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Keep away from heat, sun light and oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Specified.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Methyl Salicylate is colorless to yellowish red liquid.
Odor: Strong typical wintergreen.
Solubility: It is slightly soluble in water.
pH: NA
Specific Gravity: NA
Molecular Weight:
152.15
Molecular Formula: 2-(HO)C6H4CO2CH3
% Volatiles by volume @ 21C (70F): -
Boiling Point: 223C
Melting Point: -8.6C

10. Stability and Reactivity

Stability: Methyl Salicylate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, acids, strong bases.
Conditions to Avoid: Incompatible materials, light, dust generation, excess heat, exposure to moist air or water.

11. Toxicological Information

Acute toxicity
Harmful if swallowed. Harmful if inhaled. Irritating to skin.

Toxicity data
ORAL-RAT LD50 887 mg kg-1
ORAL-Mouse LD50 1110 mg kg-1
Dermal-Rabbit LD50 > 5.000 mg/kg

Special Remarks on Toxicity to Animals: Not available.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, OSHA.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.

12. Ecological Information

Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to algae: static test EC50 - Desmodesmus subspicatus (green algae) - 27 mg/l - 72 h
Environmental Fate: This substance is expected to have a high biological oxygen demand. It is readily biodegradable and has low bioconcentration potential.
Environmental Toxicity: NA
BOD5 and COD: Not available. This substance is expected to have a high biological oxygen demand.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: NA.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
Not regulated.
Canada TDG Classification:
Not regulated.
IATA
Not regulated.
ADR/RID
Not regulated.

15. Regulatory Information

USA:
OSHA Hazards
: Not classed as Highly Hazardous as per OSHA
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals in this material are subject to the reporting requirements
SARA 311/312 Hazards: Acute Health Hazard
Pennsylvania Right To Know Components: Methyl salicylate
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
CERCLA Hazardous Substances and corresponding RQs: Not Listed

EINECS EC Number: 204-317-7
Hazard Symbols: XN
Risk Phrases:
R-22 Harmful if swallowed.
R-36/38 Irritating to eyes and skin.
Safety Phrases:
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

WGK (Water Danger/Protection)
CAS# 119-36-8: 1

Canada - DSL/NDSL: CAS# 119-36-8 is listed on Canada's DSL List.
Canada - WHMIS: This product has a WHMIS classification of D2A.
Canadian Ingredient Disclosure List: CAS# 119-36-8 is listed on the Canadian Ingredient Disclosure List.

HMIS (Perceived): Health hazard: 1, Flammability: 1, Reactivity Hazard: 0, Physical hazards: H
NFPA (Perceived) : Health hazard: 1, Fire: 1, Reactivity Hazard: 0, Protective Equip: Goggles & Shield, Lab Coat & Apron, Gloves.

16. Other Information

H302 = Harmful if swallowed.
H319 = Causes serious eye irritation.

Xn Harmful
R22 Harmful if swallowed.
R36 Irritating to eyes.

Disclaimer:
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Our company provides this Methyl Salicylate MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Methyl Salicylate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Methyl Salicylate Manufacturers

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

Anmol Chemicals

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